Abstract

HighlightsDesign principle of a reliable electrolyte based on chelation strength is proposed for high-performance aqueous batteries.The addition of penta-sodium diethylene-triaminepentaacetic acid salt is effective in dynamically modulating anode/electrolyte interface, inhibiting water-related side reactions, and mitigating dendrite generation on zinc anodes.Symmetrical, Zn||Cu half and Zn||NH4V4O10 full cells using the new electrolyte exhibit improved electrochemical performance.

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