Abstract

Pseudostate decomposition of the first five multipole static polarizabilities of H(1s) obtained from a Givens-Householder diagonalization of (H 0 - EE0) over a N-term STO basis with orbital exponent c = 1 allows for a rapidly convergent evaluation of c 2n dispersion coefficients for H(1s)-H(1s). Twenty-five term pseudospectra with exact ψ0 give C2n values that are accurate to at least 16 significant figures up to 2 n = 14.

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