Abstract

Dipole polarizabilities of individual ionic or molecular species are computed in threedifferent liquid systems: liquid water, molten salts and magmatic melts, the last twobelonging to the class of ionic liquids. The method is based on a purely first-principlesprocedure. The liquid water polarizability tensor is found to be nearly isotropic in themolecular framework. Important environmental effects occur in the two ionic systems whenthe nature and concentration of the cations are changed. The results of these calculationswill be useful in the building of interaction potentials which include polarizationeffects.

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