Abstract

AbstractMicrostructures in InN grown on sapphire (0001) and yttria‐stabilized zirconia (YSZ) (111) by metal‐organic vapor phase epitaxy (MOVPE) were analyzed by means of transmission electron microscopy (TEM) in order to clarify the growth process. Special attention was paid to the selectivity of the crystal polarity of InN. The InN thin films grown on sapphire after nitridation has a flat surface while those grown on YSZ has hillocks on the surface. The crystal polarity was determined by comparing the experimentally observed intensity distribution in convergent beam electron diffraction (CBED) disks with those simulated by the Broch‐wave method. It was found that the InN grown on the sapphire has a nitrogen‐polarity and the one on YSZ has a mixture of In‐ and N‐polarities. The effect of surface‐nitridation of sapphire on the growth process is also discussed (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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