Abstract
We report the first experimental observation of the D(2)1Π state in the NaLi molecule. Polarisation labelling spectroscopy technique is applied to observe transitions to all vibrational levels in this state, save v=0. The inverted perturbation approach method is used to construct a pointwise potential curve for the D state, which has a small barrier (9.3cm−1) to dissociation, located at 7.98Å.
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