Abstract
The hydrothermal reaction of H3BO3, CaCO3 and H2O led to a new polar polymorphs borate, β-Ca2[B5O8(OH)]2[B(OH)3]·H2O (β-CBO). It represents the first example of alkaline-earth metal borate with the polymorph being polar one under mild hydrothermal reaction. Compared with compound α-CBO (monoclinic system) which we have synthesized before, β-CBO crystallizes in the lower triclinic system with polar space group P1. The arrangement of β-CBO is –AAAA– sequence, while α-CBO is –ABAB– sequence. Further, β-CBO is type-I phase matchable with second-harmonic generation (SHG) responses of ~1.8 times of KH2PO4 (KDP), which is larger than α-CBO (~1.3 times of KDP). The dipole moments calculations show that the larger dipole moments make β-CBO exhibit a relatively larger SHG response.
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