Point of zero charge of different carbides

Abstract

Points of zero charge, pH pzc, of various samples of NbC, WC, SiC and TiC powders were investigated using a batch equilibration method. The examined powders were both laboratory prepared (NbC and WC via plasma-chemical method (PCM), while SiC was sol–gel derived) and commercial ones (WC, TiC, and laser derived SiC). The applied solid/liquid ratio ranged from 0.1 to 0.3 g/20 ml. The aqueous solution of KNO 3 (10 −3 to 10 −1 mol/l) was used as a background electrolyte. The points of zero charge for all investigated carbides were found to be between 3.2 and 5.0. They were not affected by the concentration of KNO 3, indicating its nonspecific nature vis-à-vis studied carbides. The pH pzc values were correlated with the physicochemical properties of investigated powders.