Abstract
The conformational behavior of 2,5,5-trisubstituted 1,3,2-dioxaborinanes was studied by PMR spectroscopy. Molecules with similar substituants at C(5) are in a state of rapid ring inversion between two energetically equivalent forms. In the case of different substituents, the inversion proceeds between energetically inequivalent states with a shift in the equilibrium toward one of them.
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