Abstract

The commercially available nonionic strong base P(MeNCH2CH2)3N promotes the formation of stable and nonstable sulfur ylides from sulfonium salts at room temperature without competing [2,3] sigmatropic rearrangement. The ylides generated in situ reacted with aldehydes to give the corresponding oxiranes in high yeild. © 1999 John Wiley & Sons, Inc. Heteroatom Chem 10:538–540, 1999

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