Platonization in double-base rocket propellants

Abstract

HE inclusion of small quantities of various lead compounds in the double-base propellant system results in increased burning rate at low pressure, followed by a plateau burning region, where the burning rate remains almost independent of variation in pressure, and the postplateau region, in which the burning rate/pressure relationship is similar to that of an unleaded propellant (Fig. 1). This phenomenon of independence of burning rate to pressure, generally known as platonizatio n, implies a low value of pressure index n in the plateau region. A low value of n permits the design of lighter rocket motors because of lower safety factors. The magnitude of n is one of the important factors in determining the suitability of a propellant for rocket propulsion applications. The importance of low-pressure ballistics was realized as early as in 1939 with the widespread use of rockets. Earlier studies centered around low-energy nitrocellulose propellants with a view toward minimizing nozzle erosion, burning rate, and pressure index. However, the real impetus to the platonization of double-base propellants came from the observation that the use of lead stearate as a lubricant in the extrusion of large rocket charges actually had modified their burning characteristics. This paper reviews the literature on platonization of double-base propellant with different inorganic and organic compounds of lead and other metals, and presents various theories to explain the mechanism of the plateau effect.