Abstract
The platinum complexes Pt(PPh 3) 2 (PC 6F 5) 2 and Pt(PPh 3) 2(AsC 6F 5) 2 have been isolated from reactions of Pt(PPh 3) 3 with (PC 6F 5) 4 and (AsC 6F 5) 4 respectively. A single-crystal X-ray analysis of Pt(PPh 3) 2(PC 6F 5) 2 has shown that the compound crystallizes in space group P2 1 with a = 9.286(5), b = 20.95(1), c = 11.226(5) Å, β = 90.7(1)°, Z = 2. The structure has been solved by Patterson and Fourier methods and refined to R = 0.043 from three-dimensional diffractometer data. The complex contains the decafluorophosphorobenzene unit C 6F 5PPC 6F 5 bound through each P atom to the platinum. Coordination around the platinum is distorted square planar; the dihedral angle between the two PtP 2 planes is 20.4°.
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