Plasma-Induced Oxygen Vacancies in Urchin-Like Anatase Titania Coated by Carbon for Excellent Sodium-Ion Battery Anodes.

Abstract

The incorporation of oxygen vacancies in anatase TiO2 has been studied as a promising way to accelerate the transport of electrons and Na+ ions, which is important for achieving excellent electrochemical properties for anatase TiO2. However, wittingly introducing oxygen vacancies in anatase TiO2 for sodium-ion anodes by a facile and effective method is still a challenge. In this work, we report an innovative method to introduce oxygen vacancies into the urchin-like N-doped carbon coated anatase TiO2 (NC-DTO) by a facile plasma treatment. The superiorities of the oxygen vacancies combined with the conductive N-doped carbon coating enable the obtained NC-DTO of greatly improved sodium storage performance. When served as the anode for sodium-ion batteries, the NC-DTO electrode shows superior electrochemical performance (capacity: 272 mA h g-1 at 0.25 C, capacity retention: 98.8% after 5000 cycles at 10 C, as well as ultrahigh capacity: 150 mA h g-1 at 15 C). Density functional theory calculations combined with experimental results suggest that considerably improved sodium storage performance of NC-DTO is due to the enhanced electronic conductivity from the N-doped carbon layer as well as narrowed band gap and lowered sodiation energy barrier from the introduction of oxygen vacancies. This work highlights that introducing oxygen vacancies into TiO2 by plasma is a promising method to enhance the electrochemical property of TiO2, which also can be applied to different metal oxides for energy storage devices.