Abstract
AbstractPlanar chiral ferrocene‐fused iminium salts were synthesized in enantiomerically pure form. The novel planar chiral cyclic (amino)(ferrocenyl)carbene successfully generated from such salt was subjected to carbene trapping experiments with sulfur and copper chloride. The utility of the carbene as a chiral ligand for transition metals was preliminarily demonstrated in the copper‐catalyzed enantioselective β‐boration of an α,β‐unsaturated ester.magnified image
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