Abstract
The titanium-mediated coupling of NiII and ZnII pyrophaeophorbides results in formation of planar ethenefused bisphaeophorbides 1, M = Ni, Zn. Absorption spectroscopy indicates that the two chlorin units are highly conjugated, and the X-ray crystal structure shows the two phaeophorbide rings to be almost coplanar.
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More From: Angewandte Chemie International Edition in English
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