Abstract
Two BN-embedded p-quinodimethane derivatives were synthesized by a reaction of bis(trimethylsilyl)-1,4-dihydropyrazines, which are known as inorganic-salt-free reductants, with 9-chloro-9-borafluorene. The planar or bent structures of the resulting π-conjugated compounds were revealed by X-ray diffraction analysis. Their photophysical properties relate to their planar or bent structures due to the difference in the distribution of the HOMO.
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