Abstract

Pitting morphologies of E690 low-alloy steel in industrial and non-industrial marine splash zones are statistically analyzed, including the influence of plastic deformation. Results show that in a marine splash zone, E690 low-alloy steel experiences severe uniform corrosion and pitting corrosion, and the corrosion is more severe in the high-temperature non-industrial environment. The relationship between the pitting area changes and the depth can be well fitted to the Boltzmann cumulative distribution function to investigate the corrosion factors. In non-industrial marine splash zone, high content of chloride ions makes the metal surface have a high roughness and anodic dissolution is then promoted. The pitting depth is strongly promoted by anodic dissolution. In the marine splash zone, plastic deformation aggravates the maximum pitting depth, especially in the initial stage and in SO2-pollutant environments, although this effect gradually decreases. Pitting on low plastic deformation area in U bend samples may influenced by receiving electrons, which inhibits the protective FeOOH generation.

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