Abstract

Abstract According to VDI Guideline 3822-3 “this type of corrosion is … caused by the formation of anodic regions of slight local expansion on the electrolyte-wetted surface. The presence of protective layers (passive layers) is a prerequisite for the occurrence of pitting corrosion.” Both requirements are met on gas turbine compressor blades if water condensates on the turbine blades when the machine is at standstill and/or if the compressor temperature remains low enough in a running machine to allow aqueous media to persist, i.e. for the condensation not yet to have evaporated. This is the case with the front row of blades, generally up to stage 6. Passive layers are present on the gas turbine compressor blades, since these parts are generally manufactured from martensitic 12–16% chrome steel, as also the case for steam turbine blades and discussed in detail in other case studies in the book. The failed compressor stator blade in this case study is made of X15Cr13, material no. 1.4024. Pitting corrosion on the front row compressor blades was not uncommon before the introduction of high temperature corrosion protection coatings containing aluminium pigments on these blades. After the introduction of protective coatings, this corrosion mechanism was absent on the coated blades. The coating systems contain aluminium spherules which, given the correct coating method, are in contact with each other to form a continuous electrically conducting layer between the surface of the blade and the protective coating, creating a sacrificial anode resulting in the less noble aluminium – as compared to steel – preferentially corroding to protect the blade material. The damaged part discussed in this case study originates from an older model gas turbine commissioned in 1955 already, having accumulated almost 163000 hours of operation when the damage was diagnosed. Depending on the type of operation, this represents a period of operation of 15 to 25 years. Such compressor blades were not coated back then.

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