Abstract
Electron energy loss spectroscopy has been used to study the behaviour of piperidine adsorbed on Pd(111) as a function of temperature. The vibrational spectra indicate that piperidine is molecularly adsorbed at 100 K and is bonded to the surface via the nitrogen lone pair of electrons. Dehydrogenation to pyridine was evidenced at the surface upon room-temperature adsorption.
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