Abstract
In the title compound, C6H13N3, the C=N and C—N bond lengths in the CN3 unit are 1.3090 (17), and 1.3640 (17) (C–NH2) and 1.3773 (16) Å, indicating double- and single-bond character, respectively. The N—C—N angles are 116.82 (12), 119.08 (11) and 124.09 (11)°, showing a deviation of the CN3 plane from an ideal trigonal–planar geometry. The piperidine ring is in a chair conformation. In the crystal, molecules are linked by N—H⋯N hydrogen bonds, forming a two-dimensional network along the ac plane.
Highlights
NH2) and 1.3773 (16) Å, indicating double- and single-bond character, respectively
The piperidine ring is in a chair conformation
Molecules are linked by N—H N hydrogen bonds, forming a twodimensional network along the ac plane
Summary
Fakultät Chemie/Organische Chemie, Hochschule Aalen, Beethovenstrasse 1, D73430 Aalen, Germany. R factor = 0.045; wR factor = 0.112; data-to-parameter ratio = 15.0. C6H13N3, the C N and C—N bond lengths in the CN3 unit are 1.3090 (17), and 1.3640 (17) NH2) and 1.3773 (16) Å, indicating double- and single-bond character, respectively. The N—C—N angles are 116.82 (12), 119.08 (11) and 124.09 (11) , showing a deviation of the CN3 plane from an ideal trigonal–planar geometry. The piperidine ring is in a chair conformation. Molecules are linked by N—H N hydrogen bonds, forming a twodimensional network along the ac plane
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