Abstract

The relevant pinning centers of Abrikosov vortices in MgB2-based materials are oxygen-enriched Mg-B-O inclusions or nanolayers and inclusions of MgBx (x>4) phases. The high critical current densities, jc, of 106 and 103A/cm2 at 1 and 8.5 T, respectively, at 20 K can be achieved in polycrystalline materials (prepared at 2 GPa) containing a large amount of admixed oxygen. Besides, oxygen can be incorporated into the MgB2 structure in small amounts (MgB1.5O0.5), which is supported by Auger studies and calculations of the DOS and the binding energy. The jc of melt textured YBa2Cu3O7-δ (or Y123)-based superconductors (MT-YBaCuO) depends not only on the perfectness of texture and the amount of oxygen in the Y123 structure, but also on the density of twins and micro-cracks formed during the oxygenation (due to shrinking of the c-lattice parameter). The density of twins and microcracks increases with the reduction of the distance between Y2BaCuO5 (Y211) inclusions in Y123. At 77 K jc=8·104 A/cm2 in self-field and jc=103 A/cm2 at 10 T were found in materials oxygenated at 16 MPa for 3 days with a density of twins of 22–35 per µm (thickness of the lamellae: 45-30 nm) and a density of micro-cracks of 200–280 per mm. Pinning can occur at the points of intersection between the Y123 twin planes and the Y211 inclusions. MTYBaCuOat 77 K can trap 1.4 T (38×38×17 mm, oxygenated at 0.1 MPa for 20 days) and 0.8 T(16 mm in diameter and 10 mm thick with 0.45 mm holes oxygenated at 10 MPa for 53 h). Thesensitivity of MgB2 to magnetic field variations (flux jumps) complicates estimates of thetrapped field. At 20 K 1.8 T was found for a block of 30 mm in diameter and a thickness of 7.5mm and 1.5 T (if the magnetic field was increased at a rate of 0.1 T) for a ring with dimensions24×18 mm and a thickness of 8 mm.

Highlights

  • Both MgB2- and MT-YBaCuO bulk materials are good candidates for the same cryogenic applications

  • Our results support the conclusion that excellent SC properties of MT-YBaCuO are connected to a high extent with a high density of twins, which can be influenced by pressure-temperature conditions during the oxygenation process and by the density and homogeneous distribution of Y211 inclusions formed during melt-texturing

  • The investigation of the oxygenation process of MT-YBCO ceramics with different sizes and distributions of Y211 particles in the Y123 structure allowed us to conclude that twins influence pinning and the critical current density at elevated temperatures to a high extent, but their density as well as the density of micro-cracks parallel to the ab-plane depend to a high extent on the distances between Y211 inclusions

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Summary

Introduction

Both MgB2- and MT-YBaCuO bulk materials are good candidates for the same cryogenic applications. The manufacturing technologies for the preparation of superconducting materials with high critical current densities, jc, are very different for MgB2 and MT-YBaCuO due to the difference of their coherence lengths. Our results support the conclusion that excellent SC properties (critical current density and trapped magnetic field) of MT-YBaCuO are connected to a high extent with a high density of twins, which can be influenced by pressure-temperature conditions during the oxygenation process and by the density and homogeneous distribution of Y211 inclusions formed during melt-texturing (which, in turn, even depend on the kind of initial ingredients). It was shown that the level of trapped fields in bulk MgB2 depends to a high extent on the penetration rate of the external magnetic field into the material, because too high rates provoke flux jumps leading to a destruction of the trapped magnetic field

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