Pilot-scale investigation of the robustness and efficiency of a copper-based treated wood wastes recycling process

Abstract

The disposal of metal-bearing treated wood wastes is becoming an environmental challenge. An efficient recycling process based on sulfuric acid leaching has been developed to remove metals from copper-based treated wood chips (0<x<12mm). The present study explored the performance and the robustness of this technology in removing metals from copper-based treated wood wastes at a pilot plant scale (130-L reactor tank). After 3× 2h leaching steps followed by 3× 7min rinsing steps, up to 97.5% of As, 87.9% of Cr, and 96.1% of Cu were removed from CCA-treated wood wastes with different initial metal loading (>7.3kgm−3) and more than 94.5% of Cu was removed from ACQ-, CA- and MCQ-treated wood. The treatment of effluents by precipitation–coagulation was highly efficient; allowing removals more than 93% for the As, Cr, and Cu contained in the effluent. The economic analysis included operating costs, indirect costs and revenues related to remediated wood sales. The economic analysis concluded that CCA-treated wood wastes remediation can lead to a benefit of 53.7US$t−1 or a cost of 35.5US$t−1 and that ACQ-, CA- and MCQ-treated wood wastes recycling led to benefits ranging from 9.3 to 21.2US$t−1.