Abstract
In the structure of the title compound, C6H18N22+·2H2PO3−, the hexamethylenediammonium dication has a center of symmetry and the asymmetric unit contains half of the dication and one hydrogenphosphite anion. The (P—)O—H⋯O(—P) and N—H⋯O(—P) hydrogen bonds link ammonium and hydrogenphosphite groups to form a two-dimensional hydrogen-bonded network. Layers are linked covalently into pillars by bifunctional diammonium moieties, making a three-dimensional framework.
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