Abstract

The effects of various amounts of excess niobium ions added to the 18PMN-41PZ-41PT three-component ceramics system on the crystal structure, microstructure, polarization versus electric field, strain versus electric field and piezoelectric properties, have been studied. It was found that addition of niobium ions to 18PMN-41PZ-41PT induced a change in the crystal structure from rhombohedral to tetragonal phase. The excessive niobium ions also formed a micro-second phase which existed in the grain boundary, which could refine and uniform the grain. The refined and uniformed microstructure was found to increase the remanent polarization, saturation strain, planar coupling coefficient, Kp, and mechanical quality factor, the best value of Kp being ⩽ 69%.

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