Abstract
Cellulosic materials are attractive candidates for nature piezoelectrics. Vertically aligned cellulose nanocrystal (CNC) films are expected to show strong piezoelectricity as the largest dipole moment in CNCs exists along the cellulose chain. In this work, we adapted the confinement cell technology that was used to fabricate colloidal opal structures to align CNC rods vertically on a large scale. The high interfacial energy between the CNC-poly(tetrafluoroethylene) (PTFE) surface and torque induced by the shear force led to a large degree to the vertical alignment of CNC rods. An external DC electric field was added to further align the dipole moment of each CNC to the same direction. The as-obtained CNC film displayed excellent piezoelectric performance, and the piezoelectric coefficient was found to be 19.3 ± 2.9 pm/V, comparable to the piezoelectric coefficient d33 of poly(vinylidene difluoride) (PVDF) (20-30 pm/V). This work presents a new class of high-performance piezoelectric polymeric materials from renewable and biocompatible natural resources.
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