Abstract
The dynamics of the 1B 1 state of chromyl chloride, CrO 2Cl 2, are investigated via picosecond time-resolved measurements on a jet-cooled sample. Quasi-biexponential time evolution of fluorescence is observed for each of the nine single vibronic levels studied. A rapid, mode-dependent acceleration of the decay rates with excess vibrational energy is reported. The time dependence is described by a kinetic model and the non-radiative decay channels which may be responsible for the observed behavior are discussed.
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