Abstract
Variations of the organometallic cluster known as King's complex, [(C 5 H 5 )Fe(CO)] 4 , have been synthesized to study the excited-state transition responsible for reverse saturable absorption observed at 532 nm in this molecule. Picosecond pump-probe measurements have been used to measure the excited-state cross sections and lifetimes in King's complex and the analogs methyl-King's complex, [CH 3 (C 5 H 4 )Fe(CO) 4 ] and triethylaluminum King's complex, [(C 5 H 5 )Fe{COAl(C 2 H 5 ) 3 }] 4
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