Abstract
We review recent measurements of the recombination kinetics of geminate cation-electron pairs produced by two-photon ionization of anthracene and benzene in liquid hexane at temperatures from 191 to 296 K. Two techniques, infrared-stimulated conductivity and transient absorption by geminate electrons are compared and found to agree reasonably well. The time-dependent diffusion theory of geminate charge pair recombination is shown to provide a satisfactory fit to the decay kinetics.
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Schedule a callMore From: Radiation physics and chemistry (Oxford, England : 1993)
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