Abstract

The time-resolved fluorescence Stokes shift of α-naphthylamine in polar solvents has been measured at room temperature using a mode-locked Nd: YAG laser and a streak camera. Fluorescence spectra show a red-shift with an exponential rise time of 52 ps in isopropanol at 295 K. The rate of the relaxation process involved in the Stokes shift appears to be dependent on the extent of the change in dipole moment of the solute upon excitation.

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