Phytic-Acid-Modified Copper Foil as a Current Collector for Lithium-Ion Batteries

Abstract

Electrolytic copper foil is ideal for use in the anode current collectors of lithium-ion batteries (LIBs) because of its abundant reserves, good electrical conductivity, and soft texture. However, electrolytic copper foil is prone to corrosion in electrolytes and weak bonding to the anode substance. Surface modification of copper foil is considered an effective method of improving the overall electrochemical performance of LIBs. In this study, a 5 nm thickness phytic acid (PA)-based film is constructed on electrolytic copper foil using a fast electrodeposition process (about 10 s). PA-treated copper foil (PA-Cu) displays an improved corrosion resistance in electrolytes because of a strong complexation between the PA and copper. It is found that PA-treated copper foil also bonds better with graphite particles compared with pristine copper foil. LIBs with PA-Cu foils as their current collectors exhibit enhanced cycling stability, improved capacity retention, and superior rate performance at both low and high current densities. Our study offers a novel avenue for the development of high-performance electrode current collector materials for LIBs.