Abstract
AbstractWe have demonstrated the efficient procedure for the preparation of chitosan azo‐based amino methanesulfonate complex in isopropyl alcohol under mild condition. The ionic complexation between chitosan and {4‐[(4‐nitrophenyl)azo]phenyl}amino methanesulfonate is confirmed by ultraviolet (UV) and Fourier transform infrared spectroscopy. The circular dichroism spectra of chitosan complex showed positive at λ = 298 nm band with 3.88 mdeg having UV absorbance maximum up to a narrow band at λ= 290 nm in dimethyl sulfoxide, indicating that the polymer adopted helical (right handed) secondary structure. Physical properties, thermal stability, and surface morphology were analyzed by X‐ray diffraction, thermogravimetric analysis, differential scanning calorimetry and scanning electron microscopy. Optical properties of chitosan complex are evaluated by photoluminescence spectroscopy that showed blue shift (λem) peak at 400 nm at excitation wavelength 325 nm. Overall, it may open new perspectives for the use of chitosan azo‐based biohybrid in biomedical applications. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
