Abstract

A study of root selective adsorption of Ca, Mg, K and Na was made with rootlets of 20 species of Gramineae (from natural vegetation) exhibiting low cation exchange capacities (CEC) scattered over a narrow range 7.6–16.7 meq 100 g-1 dry matter). For each sample of rootlets successive measurements were made of its CEC (amount of Ca adsorbed from 0.05 N calcium nitrate solution) and the amounts of Ca, Mg, K and Na adsorbed from a tetracationic nitrate solution having equal concentrations (0.05 N) of each cation. Rootlet selectivity for bivalent cations increased with CEC and was greater for Ca than for Mg. In contrast, the selectivity for monovalent cations increased with decreasing CEC and was greater for K than for Na. A root's selective adsorption may therefore be governed by its CEC, in conformation with the exchange laws, as is the case with clays and resins.

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