Abstract
Ammonium 2,3,5,6-tetraoxo-4-nitropyridinate was shown to exist as stable dimers and act as a weak electrolyte in both a crystalline state and aqueous solutions. In a strongly alkaline medium, ammonium cations were successively replaced by sodium cations. The molecular and crystal structures of sodium 2,3,5,6-tetraoxo-4-nitropyridinate trihydrate and sodium ammonium bis(2,3,5,6-tetraoxo-4-nitropyridinate) monohydrate were established, and their spectroscopic characteristics were determined.
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