Physicochemical properties of microcomponents of the Kuznetsk Basin coals

Abstract

Coals are heterogeneous in nature, and they most often combine different amounts of three macerals-vitrinite, liptinite and inerinite. Vitrinite, which is responsible for the caking capacity of coal, solubility in organic solvents, mechanical properties, etc., is of decisive importance for the technological properties of coal raw materials. This paper presents the results of a study of vitrinite concentrates isolated from coal of the Kuznetsk coal basin. Using chemical and physicochemical methods of analysis (technical and elemental analyses, IR and 13C NMR spectroscopy, etc.), analytical data were obtained reflecting the change in the composition of their organic mass from the degree of coalification. It was found that with an increase in the stage of metamorphism in vitrinite concentrates, the yield of volatile substances (Vdaf) decreases, the carbon content increases from 82.2 to 88.5% and, accordingly, the content of oxygen and heteroatoms in the organic mass decreases from 11.8 to 6.2%.