Abstract
This study investigated the application of active packaging from chitosan (CS) incorporated with graphene oxide (GO) to maintain the quality and extend the storage life of palm-oil based margarine. Composite films containing various concentrations of CS (1.5 and 2.0%w/v) and GO (0, 0.5, 1.0, and 2.0%w/w CS) were produced using the solution casting method and were characterized regarding their mechanical, barrier, and antioxidant properties. For both concentrations of CS, the composite films with 2.0% GO exhibited significantly (p < 0.05) lower water vapor permeability and oxygen permeability by ~43 and ~55%, respectively. The transmittance of UV light was virtually undetectable in CSGO composites. In addition, the radical scavenging activity increased (p < 0.05) with the increasing GO concentration, as demonstrated by the 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging assay. The changes in the peroxide value (PV) and thiobarbituric acid reactive substances (TBARS) of the margarine samples were monitored for 30 d at 4 °C. The margarine sample that was wrapped with the CS1.5 GO2.0 film sample showed lower (p < 0.05) PV and TBARS values in comparison to the samples wrapped with CS1.5 and low-density polyethylene (LDPE) films. In conclusion, the CSGO composite film in this study shows great potential as an antioxidant food packaging material.
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