Abstract
The densities (d12 ) and relative permittivities (ϵ12) of liquid binary mixtures of acetonitrile-butan-l-ol and acetonitrile-butan-2-ol were measured at 288.15 K, 293.15 K, 298.15 K, 303.15 K and 308.15 K, as well as refractive indices (n D 12) at 298.15 K and surface tensions (σ12) at 293.15 K, 298.15 K and 303.15 K. From all these data, the molar volumes (V m ), apparent molar volumes (V i, φ), temperature coefficients of relative permittivities (α12) and surface tensions (k) and their deviations from ideality were calculated. Additionally, the Kirkwood's correlation factors (g K ) were found. The values of these properties are discussed in terms of interactions of acetonitrile with butan-1-ol and butan-2-ol.
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