Physicochemical modeling of the behavior of microelements (As, V, Cr, Co, and Hg) under the mixing of riverine and marine waters (the Razdol’naya River-Amur Bay System)

Abstract

By means of physicochemical modeling with the Selector software package, a model for the mixing of riverine water (pH = 7.02) and seawater was compiled and calculated. The Razdol’naya River-Amur Bay (Sea of Japan) system was assessed as an example. By means of the MINTEQA2/PRODEFA2 software package, the role of the sorption processes in riverine and marine waters, as well as in the zone of their mixing, was ascertained. The physicochemical migration forms of microelements (arsenic, vanadium, chromium, cobalt, and mercury) in the waters of the geochemical system considered and their behavior in passing through the geochemical barrier were established.