Abstract
Traditionally, polyacrylonitrile (PAN) is coated with a selective layer to tailor it for dehydrating butanol by pervaporation. But we hydrolyzed PAN with sodium hydroxide for such a purpose. Fourier transform infrared and X-ray photoelectron spectroscopy indicated that PAN׳s CN group was hydrolyzed to CONH2, which was further converted to COOH. As a result, the hydrolyzed PAN (HPAN) was made more hydrophilic, as evidenced from water contact angle data. CONH2 and COOH formed hydrogen bonds between them, causing molecular chains to rearrange (according to X-ray diffraction) and pores to shrink (shown by scanning electron microscopy). Positron annihilation lifetime spectroscopy revealed that hydrolysis led to free volume radius decrease; however, prolonged hydrolysis caused breakage of molecular chains. The HPAN produced after 4h hydrolysis exhibited narrow free volume distribution and delivered exceptional performance (water concentration in permeate=99.1wt%; permeation flux=2.03kg/m2h).
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