Physicochemical and Spectroscopic Characterization of Biofield Treated Triphenyl Phosphate

Mahendra Kumar Trivedi

doi:10.11648/j.ajac.20150305.13

Abstract

Triphenyl phosphate (TPP) is a triester of phosphoric acid and phenol. It is commonly used as a fire-retarding agent and plasticizer for nitrocellulose and cellulose acetate. The present study was an attempt to evaluate the impact of biofield treatment on physicochemical and spectroscopic properties of TPP. The study was carried out in two groups i.e. control and treatment. The treatment group was subjected to Mr. Trivedi’s biofield treatment. The control and treated samples of TPP were characterized using X-ray diffraction (XRD), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), Fourier transform infrared (FT-IR), and ultraviolet-visible (UV-Vis) spectroscopy. XRD study revealed the decrease in crystallite size (6.13%) of treated TPP that might be due to presence of strains and increase in atomic displacement from their ideal lattice positions as compared to control sample. DSC thermogram of treated TPP showed the increase in melting temperature (1.5%) and latent heat of fusion (66.34%) with respect to control. TGA analysis showed the loss in weight by 66.79% in control and 47.96% in treated sample. This reduction in percent weight loss suggests the increase of thermal stability in treated sample as compared to control. FT-IR and UV spectroscopic results did not show the alteration in the wavenumber and wavelength of FT-IR and UV spectra, respectively in treated TPP with respect to control. Altogether, the XRD and DSC/TGA results suggest that biofield treatment has the impact on physical and thermal properties of treated TPP.

Highlights

Organophosphorus compounds are comprising carbon– phosphorus bonds
Triphenyl phosphate is the triester of phosphoric acid and phenol, which is mainly used as the flame retardant agents and plasticizers [2]
The X-ray diffraction (XRD) diffractogram of biofield treated Triphenyl phosphate (TPP) showed the alteration in intensity of XRD peaks and decreased crystallite size (6.13%) as compared to control

Summary

Introduction

Organophosphorus compounds are comprising carbon– phosphorus bonds. These are mainly used for pest control as an alternative to chlorinated hydrocarbons that persist in the environment [1]. Triphenyl phosphate is the triester of phosphoric acid and phenol, which is mainly used as the flame retardant agents and plasticizers [2]. TPP reported as an electrolyte additive to improve the electrochemical performance and thermal safety of lithiumion cells. As evidenced from the literature, the thermal properties of TPP are crucial for its applications as flame retardant agent [4]. It is advantageous to find out an alternate approach that can improve the thermal stability and other physicochemical properties of TPP in order to get the more useful product. Biofield treatment was reported to alter the physicochemical properties of several metals [5, 6] and ceramics [7, 8] and spectroscopic properties of various pharmaceutical drugs like paracetamol, piroxicam, chloramphenicol and tetracycline. [9, 10]

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Results

Conclusion