Physicochemical and photocatalytic properties of biogenic ZnO and its chitosan nanocomposites for UV-protection and antibacterial activity on coated textiles

Abstract

The textiles for medical use and the purification of textile factory effluents have become the most crucial part of the human healthcare sector. In this study bioactive compounds produced by four distinct plant extracts were used for the synthesis of zinc oxide nanoparticles. The four different ZnO nanoparticles were comprehensively characterized by different analytical techniques. XRD analysis revealed the crystalline nature and phase purity of the ZnO nanoparticles. FTIR spectra provided information on the function of plant extracts in the stabilization or capping process. The size distribution and morphological diversity of the nanoparticles were further clarified by SEM and TEM images. The photocatalytic degradation activity of the four ZnO nanoparticles on two different dyes showed that ZnO nanoparticles prepared from A. indica were most effective for the degradation of 98 % and 91 % of Rhodamine B and Alizarin red dye respectively. The selected ZnO nanoparticles from A. indica were used to prepare ZnO-chitosan nanocomposites before coating on cotton fabrics. The hydrophobicity, UV protection factor, and antibacterial activity of ZnO-chitosan nanocomposites, when coated on cotton fabrics, were also examined. The overall results demonstrated the ZnO and ZnO-chitosan nanocomposite prepared in the present study as a promising material for environmental remediation application.