Abstract
Several monoazo pigments containing the residues of 3-aminophthalimide and its N- methyl and N-phenyl derivatives in the pigment molecule have been prepared. Their physicochemical and fastness properties were examined and compared with those of analogous 4-aminophthalimide pigments. Based on the observed differences in physicochemical properties and different solvent stabilities, it is suggested that the 3-aminophthalimide pigments form mostly intra-molecular hydrogen bonds whereas the 4-aminophthalimide pigments form mainly inter-molecular hydrogen bonds. THe hypothesis has been verified by the IR and UV spectra of 3- and 4-acetylaminophthalimide and of their N-methyl derivatives as model compounds.
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