Physico-Chemical Studies of Glycine, L-Alanine, L-Phenylalanine and Glycylglycine in Aqueous Triton X-100 at Different Temperatures

Abstract

Abstract The densities, ρ and viscosities, η of glycine (Gly), L-alanine (Ala), L-phenylalanine (Phe) and glycylglycine (Gly-Gly) in aqueous Triton X-100 (TX-100) solutions have been measured as a function of amino acid/peptide concentration at 298.15, 303.15, 308.15 and 313.15 K. The experimental data have been utilized to evaluate various thermodynamic parameters, viz., apparent molar volumes, V 2, partial molar volumes at infinite dilution, V 0 2, partial molar isobaric expansibilities, ϕ 0 2, partial molar volumes of transfer, Δ tr V 0 2 and A and B-coefficients of viscosity, respectively. The hydration numbers have also been calculated. The results have been discussed in terms of interactions taking place in the present systems. The structure-making/-breaking ability of the solute (amino acid/peptide) in the presence of surfactant, Triton X-100 has also been considered.