Abstract
AbstractChanges in physical and chemical properties have been studied for polycarbonate (PC) implanted by 100 keV Ni+ with various fluences from 1 × 1014 to 1 × 1016 ions/cm2. Changes in the surface morphology and composition have been observed with atomic force microscopy and X‐ray diffraction (XRD). Ni particles as precipitates in PC were observed by cross‐section transmission electron microscopy at the 100‐nm depth. Ion implantation induces changes in the topography of PC as indicated by a dramatic increase in surface roughness with ion fluence. Implanted metal ions show direct evidence of compound formation on the surface. Chemical changes in the surface region have been observed by Raman spectroscopy and UV–vis spectroscopy. UV–vis absorption analysis indicates a drastic decline in optical band gap from 5.46 to 1.76 eV at an implanted dose of 1 × 1016 ions/cm2. It is shown that partial destruction of the original chemical bonding under ion implantation leads to the creation of new amorphous and graphite‐like structures, which are confirmed by Raman spectroscopy. © 2009 Wiley Periodicals, Inc. Adv Polym Techn 27:143–151, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/adv.20130
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