Physical-chemical coupling excitation of low activity coal gasification slag solid waste and its application as a backfill cementitious material

Abstract

To realize the green mining and clean utilization of coal resources, environmental issues such as coal mine subsidence and coal gasification slag (CGS) solid waste storage require urgent resolution. High residual carbon and low activity serve as bottlenecks for CGS to achieve safe, efficient and resourceful consumption. Therefore, in this study, we proposed the concept of graded utilization of CGS and conducted a study on physical–chemical coupling to stimulate the hydration activity of CGS. We prepared a modified coal gasification slag-based cement paste backfill material (MCGS-CPB) to meet the technical requirements of coal mine backfilling. Through various experimental tests and microscopic characterization methods (uniaxial compressive strength, hydration heat and microscopic tests, etc.), we elucidated the modification mechanism of CGS, and the synergistic reaction law of MCGS-CPB was clarified. The following results were obtained. (1) The best excitation approach for CGS hydration activity was salt modification, and the early strength of MCGS-CPB prepared with CGS excited by sodium sulfate (SS) developed rapidly, while the later strengths showed expansion and deterioration. The strength development of MCGS-CPB prepared by CGS activated with calcium chloride (CC) was relatively stable, and the excitation effect was ideal. (2) The salt modification of CGS had a significant effect on the early hydration process of MCGS-CPB. The durations of the initial dissolution, acceleration, deceleration and slow reaction stages were prolonged, and the duration of the induction stage was shortened, while the hydration heat release rate increased. (3) The salt modification of CGS had a significant effect on the microstructure of MCGS-CPB, primarily due to the difference in excitation effect of salt modification on CGS on pozzolanic activity. This study provided theoretical guidance for the safe, efficient and resourceful utilization of CGS.