Abstract

Abstract Selenium-based chalcogenide glasses are best suitable materials for optical data storage due to their amorphous-to-crystalline phase transformation. Average coordination number and number of constraints for Ge10-xSe60Te30Inx (x = 0, 2, 4, 6) system have been discussed with two topological effects, floppy and rigid transition. Mean bond energy and glass transition temperature have been investigated using chemical bond approach to understand structural features of glasses. Heat of atomization, mean bond energy and glass transition temperature have been studied theoretically.

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