Abstract

Single crystals of LnAg yX 4− y (Ln=La, Ce; X=Al, Ga; y≈0.72) were synthesized by aluminum or gallium flux and characterized by single-crystal X-ray diffraction. LnAg yX 4− y (Ln=La, Ce; X=Al, Ga; y≈0.72) crystallize in the tetragonal space group I4/mmm (No. 139) with lattice parameter a=≈4.3 Å and c=≈10. 7 Å, Z=2. CeAg 0.72Al 3.28 and CeAg 0.67Ga 3.33 are metallic, and magnetic measurements indicate that they both order ferromagnetically near 3 K.

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