Abstract
In this paper, we report nanophotonic properties of single layer graphene with Zigzag and/or armchair edge in the region of Mid Infrared (Mid-IR). The photoinduced charge transfer of graphene can occur in electronic state transition of Mid-IR region, and then the transferred electrons can interact with the phonon of graphene at Mid-IR. The coupling excitation of photon and phonon (graphene plasmon) can results in photon-electron-phonon interactions, which can significantly enhance resonance Raman scattering of Mid-IR region, which is so called "graphene plasmon-enhanced resonance Raman scattering of Mid-IR region". The photoinduced charge transfers are strongly dependent on the kinds of edge structures of Zigzag and/or armchair, which are revealed by charge difference density. It is found that the edge structures of Zigzag and/or armchair play the most important role on the orientation of charge transfer. The analysis of molecular orbital Pipek-Mezey localization reveals the nature of edge structure on the occurrence or not photoinduced charge transfer. Our results can promote deeper understanding nanophotonic mechanism of Mid Infrared graphene and can be potentially used in the design of optical device based on Mid Infrared graphene.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
