Physical-chemical characterization and leaching studies involving drill cuttings generated in oil and gas pre-salt drilling activities.

Abstract

This work describes characterization and leaching studies of pre-salt drill cuttings from offshore oil and gas exploration in ultradeep waters. The metals Fe, Al, and Ba were present in the highest concentrations in drill cuttings (30000 mg kg-1, 32600 mg kg-1, and 33000 mg kg-1 respectively). The most significant contents of Ba, Al, Fe, Cu, Pb, Mn, Si, and Zn were found in cuttings containing non-aqueous fluids (NADF), but the highest concentrations of Ni and Cr were found in samples containing aqueous fluids (WBDF). The content of total petroleum hydrocarbons (TPHs) in the samples with WBDF fluids ranged from < 5.58 to 15.76 mg Kg-1 while the TPH content of the samples with NADF ranged from 28.46 to 47.16 mg Kg-1. Data on the content of unresolved complex mixtures (UCMs) and sheen tests indicated probable contamination of some cutting samples with oil. Most samples showed some degree of contamination by polycyclic aromatic hydrocarbons (PAHs). The metals present in the highest concentrations in saline and aqueous leachates were Si and Ba. The metals Cd, Cu, Ni, and Zn were present in varied concentrations in the saline leachates, and the metals Si, Ba, Cu, and Zn were found in the aqueous leachates.