Physical and mechanical properties of cement containing regional hazelnut shell ash wastes

Abstract

Turkey is ranked in the first place with two-thirds of the world hazelnut production. As the amount of shell obtained from shelled-hazelnut is almost equal to that of hazelnut by weight, the shell is a regionally important waste. The biomass is consumed as a fuel in some homes, workplaces, and public buildings with the help of specific caldrons. In the study, the use of ash was researched in the production of blended cement. For this purpose, blended cement mixtures containing hazelnut shell ash at the ratios of 0, 5, 10, 15, 20, 25 and 30% by weight of CEM I 42.5R ordinary Portland cement were prepared. The binary cementitious systems were assessed in terms of chemical, physical and mechanical properties. Hazelnut shell ash introduction increased the water demand up to 59% for standard consistency and reduced setting time up to 96% according to the ordinary Portland cement. Compressive strength results were remarkably reduced by an increase in the amount of ash. With over 5% of hazelnut shell ash introduction, the 28-d compressive strength value was found unsatisfactory (<42.5 MPa). The insufficient total amount of SiO2+Fe2O3+Al2O3 reduced the usage amount of the biomass ash in cementitious products due to having no pozzolanic characteristic. Hazelnut shell ash can be used as an alkaline set accelerator in concrete products as it is not steel-reinforced due to its high chlorine ion content.