Abstract
Ultraviolet (UV)-rearranged PIM-1 membranes have been shown to exhibit superior gas separation performance for H2/CO2 separation. The long-term aging studies of up to 100 days were investigated and revealed that the UV-rearranged PIM-1 membranes are much more stable than the original PIM-1 membrane. By positron annihilation lifetime (PAL) analyses, a constant decrease of o-Ps lifetime during physical aging of all membranes was observed, while o-Ps intensity changed sparingly. Compared to pure gas tests, the UV-irradiated PIM-1 membrane shows considerably enhanced separation performance in mixed gas tests with and without CO under high temperatures. Although the UV-rearranged PIM-1 membranes reveal deteriorating gas separation performance under humid feed conditions due to the effect of water vapor induced plasticization, the overall gas separation performance still outperforms most literature data. The successful validation of the separation performance for the UV-rearranged PIM-1 membranes under similar industrial testing conditions may possibly suggest the great potential of this type of membrane for the purification and production of industrial hydrogen.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
