Abstract
Abstract A neutral radical crystal with a two-dimensional network, namely Co(Pc)Br2 (Pc: phthalocyanine) was synthesized. Additionally, intermolecular contacts between the two-dimensional sheets, leading to isotropic semiconducting behavior, were observed. Furthermore, previously reported Co(Pc)Cl2 was revealed to have a three-dimensional network with isotropic nature and exhibited a metallic nature at 8 GPa.
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